Research Progress and Application Exploration of Conjugated Microporous Polymers in Photocatalysis
DOI: 10.23977/erej.2026.100104 | Downloads: 2 | Views: 16
Author(s)
Tangjia Xiao 1, Qi-Meige Hasi 1
Affiliation(s)
1 Chemical Engineering Institute, Northwest Minzu University, Lanzhou, China
Corresponding Author
Qi-Meige HasiABSTRACT
Conjugated microporous polymers (CMPs) have garnered significant attention in the field of photocatalysis owing to their tunable structures at the molecular level, high specific surface areas, and excellent physicochemical stability.The most recent molecular design techniques for CMPs, such as donor-acceptor (D-A) regulation, heteroatom doping, and heterostructure assembly, which allow for precise modification of their photoelectric properties, are methodically reviewed in this study. Their uses in the synthesis of hydrogen by photocatalysis and the breakdown of organic contaminants like colors and antibiotics are thoroughly examined. Numerous improvement techniques, including as heterostructure creation, morphology control, and metal doping, are suggested to solve important issues such high photogenerated carrier recombination rates. Lastly, potential research avenues for developing CMPs-based photocatalytic devices for environmental remediation and sustainable energy conversion are described.
KEYWORDS
Conjugated Microporous Polymers, Photocatalysis, Molecular Design, Environmental Energy ApplicationsCITE THIS PAPER
Tangjia Xiao, Qi-Meige Hasi. Research Progress and Application Exploration of Conjugated Microporous Polymers in Photocatalysis. Environment, Resource and Ecology Journal (2026). Vol. 10, No.1, 28-33. DOI: http://dx.doi.org/10.23977/erej.2026.100104.
REFERENCES
[1] LUO S.H., ZENG Z.T., ZENG G.M., LIU Z.F., XIAO R., XU P., WANG H., HUANG D.L., LIU Y., SHAO B.B., LIANG Q.H., WANG D.B., HE Q.Y., QIN L., FU Y.K.(2020) Recent advances in conjugated microporouspolymers for photocatalysis: designs, applications, and prospects. Journal of Materials Chemistry A, 8, 6434-6470.
[2] SHI D.H., YANG Z., GUO Y.L.(2024) Research Progress on Conjugated Microporous Polymers in Catalysis. Chemical Engineering Science and Technology, 32(06), 75-82.
[3] LUO S.H., ZENG Z.T., WANG H., XIONG W.P., SONG B., ZHOU C.Y., et al.(2021) Recent progress in conjugated microporous polymers for clean energy: Synthesis, modification, computer simulations, and applications. Progress in Polymer Science, 115.
[4] XIE L.F., NIU L., XIE T.T., LIANG L.B., ZHAO Y.X., NI Q.L., GUI L.C., WANG X.J.(2025) Regulating the Combinations of Donor and Acceptor Units via DFT Calculations for Photocatalysts with Efficient Electron–Hole Separation and Transfer Dynamics. ACS Applied Materials & Interfaces, 17(15), 22646-22656.
[5] XU X.Y., SUN Y.X., LIU J.W., LI Z.H.(2025) Rational design of novel D–A1–A2 conjugated microporous polymers for boosting spatial charge separation with enhanced photocatalytic hydrogen evolution. Separation and Purification Technology, 360(1), 130929.
[6] LI F.R., DAI X., ZHANG L.F., WU H.D., LI J.D., GUO J., YI Q.(2024) Triphenylamine promoted geometric structure adjusting of the novel macrocyclic structure D-π-A conjugated microporous polymers for photocatalytic hydrogen evolution. Fuel,370,131812.
[7] ZHANG J., XU Z.C., YU Z.D., XIANG T., YAN H.J., CHEN H., ZHU T.R.(2026) Preparation of Thiophene-Based Conjugated Microporous Polymers and Their Photocatalytic Hydrogen Production Performance. New Materials for Chemical Industry, 1, 1-12.
[8] JIN S.L., HAN CH.ZH., ZHANG CH., HU D.D., JIANG J.X.(2025) Study on photocatalytic hydrogen production performance of furan-based D-π-A conjugated microporous polymers with tunable donor/acceptor ratios. Acta Polymerologica Sinica, 56(10), 1841-1849.
[9] DENG ZH.ZH.(2024) Regulation of Built-in Dipole Moments and Photocatalytic Performance of Conjugated Microporous Polymers. Hunan University of Science and Technology.
[10] ZHAO Q., CAO J.J., ZHANG Z.H., MA X.K., SONG L.Q., WANG J., ZHAO M.W.(2025) S-Scheme TpPa/C6N7 heterobilayer: conjugated microporous polymers/covalent organic frameworks-based photocatalyst for efficient overall water splitting. Journal of Colloid and Interface Science, 702(Pt 2), 138981.
[11] ZHENG Y.X., YOU S.J., LI S.S., DING Z.X., YUAN R.S., LONG J.L., XU C.(2025) All‐Conjugated Microporous Polymer Heterojunction with Hierarchical Hollow Sphere Architecture for Photocatalytic H2O2 Production. Advanced Functional Materials, 36(7), e08538.
[12] XU X.Y., LIU J.W., SUN Y.X., LI Z.H.(2025) Molecular engineering of novel D−A1−A2 conjugated microporous polymers by efficient electron donor for highly enhanced photocatalytic hydrogen generation. Separation and Purification Technology, 364(P2), 132454.
[13] CAN L., GONG H., YE G., MURUGAN P., XIE Z.H., DAI Y.F., YANG K., YU C.L., LIU S.Y.(2025) D1-D2-A ternary conjugated microporous polymers synthesized via direct CH arylation for enhancing photocatalytic hydrogen evolution. Journal of Colloid and Interface Science, 688.
[14] YU J.L. (2024) Preparation and Photocatalytic Performance Study of Conjugated Microporous Polymer Hollow Microsphere-Based Composite Materials. Northwest Minzu University.
[15] DENG Z.Z., ZHANG W.J., SUN P.H., ZHAO H.W., CAO X.X., LI G., LIU Q.Q.(2024) Donor polarization engineering of conjugated microporous polymers to boost exciton dissociation for photocatalytic degradation of tetracycline. Chemosphere, 364, 143236.
[16] ZHANG W.J., SUN P.H., WANG B.X., LI S.T., YI B., LIU Q.Q., YANG H.(2024) Polarization engineering of conjugated microporous polymers to boost exciton dissociation by dielectric constant regulation for photocatalytic degradation of antibiotics. Separation and Purification Technology, 332.
[17] ZHAO K., TANG Z.Y., XU Z.J., LIU L.T., HUANG F.H., YI B., YANG H.(2025) Boosting exciton dissociation in conjugated microporous polymers via molecular isomerization for photocatalytic degradation of antibiotics. Separation and Purification Technology, 357(PA), 130016.
[18] YU J.L., HASI Q.M.G., GUO Y.Y., SONG L.Y., YIN M., MA L.N., HAN Z.C., XIAO C.H., ZHANG Y.H., CHEN L.H.(2024) Porphyrin-Based Conjugated Microporous Polymer Loaded with Nanoscale Zerovalent Iron for the Degradation of Organic Pollutants under Visible Light. Langmuir, 40(9), 4739-4750.
[19] WU W.(2024) Design and Synthesis of Novel Conjugated Microporous Polymers and Their Performance in Gas-Phase Photocatalytic Reduction of Low-Concentration CO2. Donghua University of Technology, Nanchang.
[20] YU S.S.(2024) Design Synthesis of Biomimetic Conjugated Microporous Polymers and Investigation of Their Photocatalytic Reduction of Uranium(VI) Performance. Donghua University of Technology, Nanchang.
| Downloads: | 6307 |
|---|---|
| Visits: | 539631 |
Sponsors, Associates, and Links
-
International Journal of Geological Resources and Geological Engineering
-
Big Geospatial Data and Data Science
-
Solid Earth and Space Physics
-
Environment and Climate Protection
-
Journal of Cartography and Geographic Information Systems
-
Offshore and Polar Engineering
-
Physical and Human Geography
-
Journal of Atmospheric Physics and Atmospheric Environment
-
Trends in Meteorology
-
Journal of Coastal Engineering Research
-
Focus on Plant Protection
-
Toxicology and Health of Environment
-
Geoscience and Remote Sensing
-
Advances in Physical Oceanography
-
Biology, Chemistry, and Geology in Marine
-
Water-Soil, Biological Environment and Energy
-
Geodesy and Geophysics
-
Journal of Structural and Quaternary Geology
-
Journal of Sedimentary Geology
-
International Journal of Polar Social Research and Review

Download as PDF